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Oddsmakers tip City to click into gear against Serie A outfit Atalanta, while struggling Spurs should get their season back on track against Red Star Belgrade in north London. Meanwhile, holders Liverpool are away to Genk in Group E on Wednesday, while Chelsea travel to last season's beaten semi-finalists Ajax.
Spain's big two are also in action with record winners Real Madrid in Galatasaray on Tuesday, while Barcelona's terrific front three of Lionel Messi , Luis Suarez and Antoine Griezmann will be too much for Sparta Prague in the capital of the Czech Republic a day later.
Dinamo Zagreb, p. Bayer Leverkusen, p. Paris Saint-Germain, 8 p.
ET Group A: Galatasaray vs. Real Madrid, 8 p. ET, Group B: Olympiacos vs.
Bayern Munich, 8 p. Red Star Belgrade, 8 p. Atalanta, 8 p. Lokomotiv Moscow, 8 p. Zenit St. Petersburg, p. Chelsea, p.
Napoli, 8 p.
ET Group E: Genk vs. Liverpool, 8 p. Borussia Dortmund, 8 p. Barcelona, 8 p. Lyon, 8 p.
The teams and at least some of their fans have travelled all the way to Baku in Azerbaijan for this, but thankfully you don't have to - keep reading and we'll tell you how you can watch every minute of the game with a Chelsea vs Arsenal live stream from absolutely anywhere on Earth.
ET Group G: Lille vs. Valencia, 8 p. The domestic rivals will make easy work of their home fixtures on Matchday 3. City have too much quality in the advanced areas of midfield for Atalanta to cope with.
Kevin De Bruyne and Bernardo Silva can unlock defences from multiple angles, while David Silva is defying father time to put together some exceptional performances.
Gabriel Jesus started in his place and scored, but the Argentina international remains the main man up top in Pep Guardiola's squad.
The Egypt international missed Sunday's draw at Manchester United with an ankle problem. Fortunately for the Anfield side, there is more creativity in midfield, with Alex Oxlade-Chamberlain and Adam Lallana fit again.
The former Southampton man netted the equaliser at Old Trafford and can help Liverpool manufacture a few more chances against Genk, enough to win by a comfortable margin. What a time to get it!
The brilliance of Messi and Suarez has been taken as a guarantee, but it's been a different story for Griezmann. Facebook Logo.